The Black Dragon can breathe corrosive and poisonous fumes which can burn skin and hair, and choke a man to death.
Source: Warhammer Fantasy: 6th Edition
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This is a breath weapon. Hits are resolved at Strength of 4 and any unit taking casualties from the noxious breath must pass a Leadership test in order to declare charges next turn.
Undead and Daemons are not affected by this additional penalty, nor are troops that are Immune to Psychology, although they still suffer damage as normal.