At the heart of Archaon's army is his old warband, the words of Chaos. Only the strongest have prevailed in his long quest, leaving a cadre of hardened troops.
Source: Warhammer Fantasy: 6th Edition
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Archaon's army must include at least one unit of Knights of Chaos, and they must be upgraded to Chosen status. They may not exchange their Mark of Chaos Undivided. Archaon is the only character allowed to join this unit (though he does not have to). In addition, if Archaon leads unit, then it also becomes Immune to Psychology.